The Molecular and Electronic Structure of Tris(dimethylarsino)amine (Me2As)3N

DFT and HF Studies: Geometry, Hydrogen Bonding, Vibrational Frequencies and Electronic Properties of Enaminones and Their Complexes with Transition Metals

Enaminones are those structures made up three various functional groups including carbonyl, alkeneand amine groups which arelocated along with each other in a conjugate fashion. These compoundsare of much attention due to special characteristics and numerous applications. In the paper, sixvarious enaminone structures were theoretically optimized and after concluding, were compared withequivalen...

Synthesis and Electronic Properties of Tris(4-formylbiphenyl-4-yl) Amine as a Building Block for Covalent Organic Frameworks and for Optoelectronic Devices

Herein is reported the preparation of a new triphenylamine derivative, the tris( ́4-formylbiphenyl-4-yl) amine (TFBA). This compound exhibits optoelectronic properties suitable for its use in Dye-Sensitized Solar Cells (DSSCs) and light emitting diodes. The electrochemical properties were studied by cyclic voltammetry (CV) and square wave voltammetry (SWV). At the same time, the symmetrical chem...

Bis(dicyanamido-κN)[tris­(3-amino­propyl)amine-κ4 N]nickel(II)

In the title complex, [Ni(C2N3)2(C9H24N4)], the Ni(II) atom is coordinated in a distorted octa-hedral geometry by one tris-(3-amino-prop-yl)amine (tris-apa) ligand and two dicyanamide (dca) ligands [one of them disordered in a 0.681 (19):0319 (19) ratio]. Inter-molecular N-H⋯N hydrogen bonds involving the N atoms of the dca anions and the tris-apa amine H atoms result in the formation of a thre...

The Molecular Structure of Tris(dimethylstibino)amine

A Novel Approach for Preparation of Acetylacetonate Complex Anchored to High Order Nanoporous Silica (LUS-1)

Tris(3-bromo-acetylacetonato) chromium(III) as an inert and very stable complex with a good leaving group was synthesized using as-prepared Cr(acetylacetonate)3. Highly ordered nanoporous silica (LUS-1), with some great features, was functionalized with 3-aminopropyltriethoxysilane. Then the as-prepared product was modified with tris(3-bromo-acetylacetonato) chromium(III) under mild reaction co...